The use impression without of having the being attached and the wa being attached when drying where this invention with former hair make-up charge was not obtained vis-a-vis the hair and the especially damage hair, when using expresses and the hair make-up charge which is superior in pliability and the preservation water effect, are offered with economic method. Furthermore details according to this invention, produce the composition which contains the cation conversion toreharosu derivative of cation conversion toreharosu and cation conversion gurikoshirutoreharosu etc, can obtain the satisfactory use impression and the hair make-up charge which is superior in pliability and the preservation water effect by combining to hair make-up charge without passing refinement process.本発明は、毛髪、特に損傷毛髪に対して、従来の毛髪化粧料では得られなかった、使用時のべたつきや乾燥時のごわつきのない使用感と柔軟性、保水効果に優れた毛髪化粧料を、経済的な方法で提供する。さらに詳しくは、本発明によれば、カチオン化トレハロースおよびカチオン化グリコシルトレハロース類などのカチオン化トレハロース誘導体を含有する組成物を製造し、精製過程を経ることなく毛髪化粧料に配合することにより、良好な使用感と柔軟性、保水効果に優れた毛髪化粧料を得ることができる。