PROBLEM TO BE SOLVED: To provide an inexpensive and simple method and apparatus for selectively recovering gallate-type catechins from non-polymer catechins.SOLUTION: An aqueous solution containing non-polymer catechins is passed through a column 14 packed with a weakly acidic cation-exchange resin containing a carboxylic acid functional group to contact the aqueous solution containing non-polymer catechins with the weakly acidic cation-exchange resin and adsorb the gallate-type catechins in the aqueous solution containing non-polymer catechins. Thereafter, the weakly acidic cation-exchange resin is brought into contact with an eluting solution to elute the gallate-type catechins from the resin and recover the eluted gallate-type catechins.COPYRIGHT: (C)2012,JPO&INPIT【課題】非重合体カテキン類からガレート型カテキンを選択的に回収するための安価で簡便な方法及び装置を提供する。【解決手段】カルボン酸の官能基を含む弱酸性陽イオン交換樹脂を充填したカラム14に非重合体カテキン類含有水溶液を通液して、非重合体カテキン類含有水溶液と該弱酸性陽イオン交換樹脂とを接触させ、非重合体カテキン類含有水溶液中のガレート型カテキンを吸着処理した後、該弱酸性陽イオン交換樹脂と溶離液とを接触させ、該樹脂からガレート型カテキンを溶離させ、ガレート型カテキンを回収する。【選択図】図1