A method for manufacturing chlorine dioxide gel includes the steps of: (1) dissolving peg-copolymer bis-decyltetradeceth in hot water to form an aqueous solution of peg-copolymer bis-decyltetradeceth; (2) heating the aqueous solution of peg-copolymer bis-decyltetradeceth obtained in the above step to form a gel like colloid; (3) dissolving pure chlorine dioxide gas in water to form an aqueous solution of chlorine dioxide; and (4) uniformly mixing the aqueous solution of chlorine dioxide and the colloid of peg-copolymer bis-decyltetradeceth to form a chlorine dioxide gel, whereby with the above steps, a method for manufacturing chlorine dioxide gel that stably preserves chlorine dioxide gas in a gel is provided. Step (2) may be carried out by heating the aqueous solution of peg-copolymer bis-decyltetradeceth to 90ºC. Step (4) may be carried out when the colloid of peg-copolymer bis-decyltetradeceth has been cooled down to 30ºC.