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PROCÉDÉ DE SULFINYLATION D'UN DÉRIVÉ PYRAZOLE
专利权人:
BASF AGRO B.V.; ARNHEM (NL); ZUERICH BRANCH
发明人:
申请号:
EP07822220.5
公开号:
EP2081908B1
申请日:
2007.11.05
申请国别(地区):
EP
年份:
2013
代理人:
摘要:
The present invention relates to a process for the sulfinylation of a pyrazole derivative, characterized in that 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazole-3-carbonitrile (II) is reacted with a sulfinylating agent selected from trifluoromethylsulfinic acid, trifluoromethylsulfinic acid anhydride, and a trifluoromethylsulfinate alkaline or alkaline earth metal salt and mixtures of the acid and/or the salt(s), in the presence of at least one amine acid complex wherein the amine(s) are selected from tertiary amines and the acid(s) are selected from hydrofluoric, hydrochloric, hydrobromic and hydroiodic acid and sulfonic acid derivatives, and with the addition of a halogenating agent.
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