Claim 1: including a process of Outline 1 (I) to make compound (1) react with compound (2a) to produce compound (2b);Then (2) the formula compound (2b) reacts with the formula compound (2C) to produce the formula compound (3);Then (3) recycle the formula compound (3) with dehydrating agent to produce the formula compound (4);wherein (A) each R¹ is independently selected from H, F, Cl, Br, I, CN, NO₂ and substituted or unsubstituted C₁₋₆ alkyl, wherein each substituted R¹ has one or more selected substituents, independently, of F, Cl, Br, I, CN, NO₂,C₁₋₆ alkyl and C₁₋₆ haloalkyl;(B) R² is selected from substituted or unsubstituted C₁₋₆ alkyl, substituted or unsubstituted C₂₋₆ alkenyl, substituted or unsubstituted C₁₋₆ alkoxy, substituted or unsubstituted C₂₋₆-oxy alkenyl, C₃₋₁₀- cycloalkyl substituted or unsubstituted oxy, substituted or unsubstituted C₃₋₁₀-oxy cycloalkenyl, substituted or unsubstituted C₆₋₂₀-oxy aryl, substituted or unsubstituted C₁₋₆-aryl alkyl and substituted or unsubstituted C₁₋₂₀-heterocyclyl , wherein each R² substituted has one or several substituents independently selected from F, Cl, Br, I, CN, NO₂,1. Lease land No. c833218331 and 832626;C₂₋₆ alkenyl,C₁₋₆ haloalkyl,haloalkenyl C₂₋₆,haloalquil C -oxi haloalquenil C -oxi cicloalquilo Ccycloalkenyl C₃₋₁₀,C₃₋₁₀ halocycloalkyl,halocicloalquenilo C₃₋₁₀,arilo C y heterociclilo C(C) R³ is selected from H, substituted or unsubstituted C₁₋₆ alkyl, substituted or unsubstituted C₃₋₁₀-oxy cycloalkyl, substituted or unsubstituted C₁₋₆-cycloalkyl, substituted or unsubstituted Cilo aryl substituted and C₁₋₆-C₆₋₂₀-substituted or unsubstituted alkyl, wherein each substituted R³ has one or more substituents independently selected from F, Cl, Br and I; and (D) R⁴ is selected from H, substituted or unsubstituted C₁₋₆ alkyl, substituted or unsubstituted C₃₋₁₀-oxy cycloalkyl, substituted or unsubstituted C₁₋₆-cycloalkyl alkyl,C₆₋₂₀-oxy substituted or unsubstituted aryl, C₁₋₆-substituted or unsubstituted C₁₋₆-aryl