Protonowe ciecze jonowe z kationem 1-(N-propylo-N-(2-(2,4,6-trichlorofenoksy)etylo)karbamoilo) imidazoliowym i anionem organicznym, sposób ich otrzymywania oraz zastosowanie jako fungicydy
the subject invention are proton ion liquids with kationem 1 - (n - propyl - n - (2 - (2,4,6-trichlorophenoxy) ethyl) carbamoyl) imidazoliowym and anionem organic way their receive and use as fungicides in cereal crops and oilseed rape.protic ionic liquids with kationem 1 - (n - propyl - n - (2 - (2,4,6-trichlorophenoxy) ethyl) carbamoyl) imidazoliowym represents the general formula 1, in which a means anion organic formate or salicylate or benzoate or chloroacetate or propionate or acetate.process to obtain liquid ion above is that n - propyl - n - [2 - (2,4,6-trichlorophenoxy) ethyl] imidazole - 1 - karboksyamid undergo reaction with the aqueous solution protonowania chloroworodowego acid concentration of at least 1% in a mole ratio of n - propyl - n - [2 - (2,4,6-trichlorophenoxy) imidazole ethyl] - 1 - trifluoroacetate to factor protonuj\u0105cego ranging from 1: 0.95 to 1: 1.05,good 1: 1, in an organic solvent, acetonitrile or methanol or isopropanol or ethanol, preferably acetonitrile, at a temperature of from 20 to 70\u00b0c by time of at least 1 minutes, after which the vaporized solvent, and subsequently the mixture is dissolved in a solvent poreakcyjn\u0105 organic: methanol or isopropanol or acetonitrile or ethanol.advantageously the methanol and subjected to reaction of nitrate with sodium salt or potasow\u0105 formic acid or acetic acid or acid chlorooctowego or propioniowego acid or salicylic acid or benzoic acid, during at least 1 minutes, after which ods\u0105cza are formed by product sodium chloride or potassium chloride, filtrate vaporized solvent.and the product dried under reduced pressure.Przedmiotem wynalazku są protonowe ciecze jonowe z kationem 1-(N-propylo-N-(2-(2,4,6-trichlorofenoksy)etylo)karbamoilo)imidazoliowym i anionem organicznym, sposób ich otrzymywania oraz zastosowanie jako fungicydy w uprawach zbóż i rzepaku. Protonowe ciecze jonowe z kationem 1-(N-propylo-N-(2-(2,4,6-trichlorofenoksy)etylo)karbamoilo)imidazoliowym przedstawia wzó
