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Developing fatigue-resistant ferroelectrics using interlayer sliding switching

作   者:
Renji BianRi HeEr PanZefen LiGuiming CaoPeng MengJiangang ChenQing LiuZhicheng ZhongWenwu LiFucai Liu
作者机构:
China||State Key Laboratory of Electronic Thin Films and Integrated Devices University of Electronic Science and Technology of China China||Department of PhysicsShanghai Frontiers Science Research Base of Intelligent Optoelectronics and PerceptionSchool of Information Science and Technology Xi Chang University Ningbo 315201Key Laboratory of Magnetic Materials Devices & Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology Department of Materials Science Chengdu 611731 Xi Chang 515013 China||State Key Laboratory of Photovoltaic Science and Technology Fudan University China||Key Laboratory of Liangshan Agriculture Digital Transformation of Sichuan Provincial Education Department Ningbo Institute of Materials Technology and Engineering Huzhou 313001 Chinese Academy of SciencesSchool of Optoelectronic Science and Engineering China||Suzhou Institute for Advanced Research Xi Chang 615013 China China||Yangtze Delta Region Institute (Huzhou) University of Science and Technology of China Suzhou 215123 Hefei 230026 Institute of Optoelectronics Shanghai 200433
期刊名称:
Science
i s s n:
0036-8075
年卷期:
2024 年 385 卷 Jul.5 TN.6704 期
页   码:
57-62
页   码:
摘   要:
Ferroelectric materials have switchable electrical polarization that is appealing for high-density nonvolatile memories. However, inevitable fatigue hinders practical applications of these materials. Fatigue-free ferroelectric switching could dramatically improve the endurance of such devices. We report a fatigue-free ferroelectric system based on the sliding ferroelectricity of bilayer 3R molybdenum disulfide (3R-MoS_2). The memory performance of this ferroelectric device does not show the wake-up effect at low cycles or a substantial fatigue effect after 10~6 switching cycles under different pulse widths. The total stress time of the device under an electric field is up to 10~5 s, which is long relative to other devices. Our theoretical calculations reveal that the fatigue-free feature of sliding ferroelectricity is due to the immobile charge defects in sliding ferroelectricity.
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