Beryllium‐Mediated Halide and Aryl Transfer onto Silicon

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作   者：

Carsten Hänisch;  Magnus R. Buchner;  Fabian Dankert;  Chantsalmaa Berthold;  Matthias Müller; 

作者机构：

Philipps-Universität Marburg; 

关键词：

Lewis Acid;  ring opening;  silicon;  beryllium;  silanolate; 

期刊名称：

Chemistry: A European journal

i s s n：

0947-6539

年卷期：

2023 年 29 卷 66 期

页   码：

n/a-n/a

页   码：

摘   要：

Abstract The reactivity of hexamethylcyclotrisiloxane (D3) towards BeCl2, BeBr2, BeI2 and [Be3Ph6]3 was investigated. While BeCl2 only showed unselective reactivity, BeBr2, BeI2 and [Be3Ph6] cleanly react to the trinuclear complexes [Be3Br2(OSiMe2Br)4], [Be3I2(OSiMe2I)4] and [Be3Ph2(OSiMe2Ph)4]. These unprecedented bromide, iodide and phenyl transfer reactions from a group II metal onto silicon offer a versatile access to previously unknown diorgano bromo and iodo silanolates.