Isolation, characterization, and molecular structure of 1,2-(Me2S)(2)B12H10

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作   者：

Kultyshev RG.;  Meyers EA.;  Shore SG.;  Liu JP.; 

作者机构：

OH 43210;  USA.;  120 W 18Th Ave;  Ohio State Univ;  Columbus;  Dept Chem; 

关键词：

Boranes; 

期刊名称：

Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics

i s s n：

0020-1669

年卷期：

1999 年 38 卷 21 期

页   码：

4913-4915

页   码：

摘   要：

The pyrolysis of BH3. SMe2 at 130 degrees C and 1000 psi yields isomers of (Me2S)(2)B12H10. The previously unreported 1,2 isomer has been isolated and characterized by single-crystal X-ray analysis and multinuclear NMR spectroscopy. Its physical and spectral characteristics are compared to those of the earlier reported 1,7 and 1,12 isomers of (Me2S)(2)B12H10.