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Nature-Derived Flame Retardant for Cotton Fabrics with Green Coconut Shells

作   者:
Tarikul IslamAbdullah Al Rakib ShikderMd. Shahabul HossenMd Mazbah UddinMd Tanvir Hossainand M. Mahbubul Bashar
作者机构:
Dhaka 1216 andInteriorsUnited States Department of TextileEngineering Bangladesh University of Business andTechnology Mawlana Bhashani Science and TechnologyUniversity JashoreUniversity of Science and TechnologyDepartment of TextilesDepartment of Materials Science andEngineering Georgia 30602 Jashore 7408 Tangail 1902Tangail 1902 Bangladesh MerchandisingDepartment of TextileEngineering University of Georgia Michigan Technological UniversityDepartment of Textile Engineering United States AthensBangladesh Department of Textile EngineeringMichigan 49931Mawlana Bhashani Science and Technology Universityand Interiors Houghton
关键词:
phytic acidflame retardantcotton fabricgreen coconut shell (GCS) extractwashing durabilitylimiting oxygen index (LOI)
期刊名称:
ACS Chemical Health & Safety
i s s n:
年卷期:
2025 年 32 卷 1 期
页   码:
57-65
页   码:
摘   要:
This study presents an eco-friendly flame-retardant solution for cellulosic fabrics using green coconut shell (GCS) extract and phytic acid (PA). Cellulosic materials are highly flammable and release harmful gases during combustion. Conventional flame retardants may pose environmental and health risks while impacting the fabric quality. GCS extract is a rich source of tannins, phosphorus, silicates, metallic salts, and oxides and is explored as a novel flame retardant (FR) for cotton fabrics. Cotton samples were pretreated with PA and then with varying concentrations of GCS extract using a padding technique. Comprehensive characterization followed, including limiting oxygen index (LOI), thermogravimetric analysis (TGA), derivative thermogravimetry (DTG), burning time tests, scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, Fourier-transform infrared spectroscopy (FTIR), tensile strength, and wash durability assessments. The treated samples exhibited improved flame resistance properties, with LOI values increasing from 18 to 29.5. TGA results indicated enhanced thermal stability, while FTIR analysis confirmed higher phenolic hydroxyl content in treated samples. SEM imaging verified GCS extract deposition and EDX analysis revealed key elements such as Na, Al, P, S, K, and Ca on the treated surfaces. The combination of GCS extract and PA offered a sustainable and effective flame-retardant solution for cellulosic fabrics. The naturally sourced elements help to enhance fire resistance while preserving environmental and material integrity.
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