A multilayer film comprising: (a) an interior layer of homogeneous ethylene/alpha-olefin copolymer or a blend of homogeneous ethylene/alpha-olefins copolymers having a density from 0.89 to 0.92 grams per cubic centimeter (b) a first exterior layer of a homopolymer or copolymer of polypropylene, a blend of homopolymer or copolymer of polypropylene and elastomer, high density polyethylene, or copolyester and (c) a second exterior layer of a polyamide, copolyamide, polyester, copolyester, high density polyethylene, polypropylene, propylene/ethylene copolymer, or polycarbonate. The multilayer film is advantageously used to produce flexible pouches for the packaging and administration of medical solutions.