The patent provides a superabsorbent polymer hydrogel xerogel sponge and a preparation method and an application thereof. The sponge is a three-dimensional network porous sponge with chitosan as its skeleton, superabsorbent polymer as its branched chain, and macromolecule or polymer with flexible structure as its cross-linking agent. The sponge can be prepared by a one-pot method. The product has porous structure, having the characteristic of superabsorbent and maintaining integrity and certain mechanical strength after water absorption. The material can be used in the emergency hemostasis of large arteriovenous hemorrhage. The effect is better than that of the existing materials in the market. The superabsorbent hydrogel xerogel sponge provided by the invention has the advantages of simple preparation process, low cost. The product has outstanding hemostatic effect, good safety, with no heat production and no residue, and has significant medical value and industrial potential.