The present invention relates to a novel herbicidal composition comprising a hcrbicidal active ingredient combination of prosulfocarh and at least one other herbicide selected from naproanilide, napropamide, diphenamid, butachlor, acctochlor, dimcthcnamid, dimethachlor. alachlor, mclolachlor, S-metolachlor, propisochlor, pethoxamid, metazachlor, thenylchlor, propachlor, fentrazamide, flufcnacet. mefenacel, anilofos, piperophos and catcnslrolc. llach combination is suitable for the selective control of undcsired vegetation like weeds (grasses and broad-leaved weeds) in crops of useful plants, for example in crops of rice, cereals and maize.