PURPOSE: A manufacturing method of a phenyl carbamate derivative is provided to manufacture a phenyl carbamate which has little toxicity and excellent muscle releasing effect capable of treating a central nervous system injury in various screening model. CONSTITUTION: A manufacturing method of a phenyl carbamate derivative represented by chemical formula 1 includes a step of conducting a carbamation reaction by the reaction of a compound represented by chemical formula 6 and a chlorosulfonyl isocyanate. In the chemical formulas, X is independently at least one element selected from halogens, n is an integer from 1-5, and R1 is a linear or branched C1-C10 alkyl group.중추신경계 장애 치료에 유용한 페닐 카바메이트 유도체의 제조방법, 페닐 카바메이트 유도체 제조의 중간체, 상기 중간체의 제조방법을 제공한다.