A dental agent that is applied to a dental substrate is disclosed and includes: at least one breakable capsule, microcapsule or combination thereof, wherein the at least one breakable capsule, microcapsule or combination thereof comprises at least one adhesive primer, or a combination thereof. Methods of applying contemplated dental agents are also disclosed that include: providing a dental agent, wherein the dental agent comprises at least one breakable capsule, microcapsule or a combination thereof, providing a dental substrate, applying the dental agent to the dental substrate, and breaking the at least one breakable capsule, microcapsule or combination thereof on the surface of the dental substrate.
