A sampling device includes a sampling unit, an switching valve, and a container unit. The sampling unit includes a connecting end, an inflow port corresponding to the connecting end, an engaging portion opposite to the connecting end, and an outflow port corresponding to the engaging portion. The switching valve is mounted on the sampling unit. By manipulating the switching valve, a blockage is generated between the inflow port and the outflow port or communication is generated between the inflow port and the outflow port. The container unit includes an outer bottle member detachably connected to the engaging portion, an inner bottle member disposed inside the outer bottle member, and an elastic member. The outer bottle member has at least one visible portion, through which the inside of the outer bottle member can be seen. The inner bottle is made of a transparent material. The use of the container unit as a whole can achieve the purposes of sampling and safe operation.一種取樣裝置,包含一取樣單元、一開關閥及一容器單元。該取樣單元包括一連接端、一對應於該連接端的引入口、一相反於該連接端的銜接部及一對應於該銜接部的流出口,該開關閥安裝於該取樣單元,操作該開關閥可使該引入口與該流出口之間產生阻斷或使該引入口與該流出口之間產生連通,該容器單元包括一可拆卸地連接於該銜接部的外瓶件、一容置於該外瓶件內部的內瓶件及一彈性件,該外瓶件具有至少一可透視至內部的可視部,該內瓶件採用可透視材質製成。利用該容器單元整體的配合,可達到取樣目的及操作安全之目的。