Are provided a novel organic-inorganic complex showing excellence in ultraviolet (UV) blocking effects, a manufacturing method thereof, and an UV blocking agents manufactured by using the same, and more specifically, there are provided a novel organic-inorganic complex capable of making up for the disadvantages of existing organic UV sunscreen materials and existing inorganic UV sunscreen materials, and increasing the advantages thereof, and a method of effectively manufacturing the organic-inorganic complex with a high yield of production, and an UV blocking agents manufactured by using the same.