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CURABLE COMPOSITION
专利权人:
发明人:
INATA, KAZUMASA,稻田和正,稻田和正,HASHIMOTO, NAOKI,桥本□树,橋本□樹,YACHI, KENTARO,谷内健太郎,谷內健太郎
申请号:
TW106123777
公开号:
TW201829537A
申请日:
2017.07.17
申请国别(地区):
TW
年份:
2018
代理人:
摘要:
An object of the present invention is to provide a curable composition having fast curabilitiy, and that can make a cured layer having low yellowing, high flex resistance, and low curl properties. The curable composition of the present invention includes a mixture (A) of compounds having (meth)acryloyl group obtained by transesterification of a polyglycerin having a hydroxy value of 700 to 1,200 mgKOH/g and a compound having one (meth)acryloyl group with catalysts X and Y below. catalyst X : one or more kinds of compounds selected from the group consisting of a cyclic tertialy amine having an azabicyclo structure, or a salt thereof or a complex thereof, amidine, or a salt thereof or a complex thereof, a compound having a pyridine ring, or a salt thereof or a complex thereof, and a phosphine, or a salt thereof or a complex thereof. catalyst Y : a compound include zinc.本發明提供一種具快速硬化性且硬化膜具有優異之低黃變性、高撓曲性及低卷曲性的硬化型組成物。本發明之硬化型組成物含有具(甲基)丙烯醯基之化合物的混合物(A),該具(甲基)丙烯醯基之化合物係以下述方式製得:於下述催化劑X及Y存在下,使羥值為700~1,200mgKOH/g之聚丙三醇與具1個(甲基)丙烯醯基之化合物進行酯交換反應;其中,催化劑X:選自於由具氮雜雙環結構之環狀3級胺或其鹽或錯合物、脒或其鹽或其錯合物、具吡啶環之化合物或其鹽或錯合物、以及膦或其鹽或錯合物所構成群組中之一種以上化合物;催化劑Y:含鋅化合物。(無)
来源网站:
中国工程科技知识中心
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