The present disclosure is directed to solvent compositions comprising volatile organic compounds (VOC) having a low volatility which are classified as VOC-exempt by many countries. Combinations of an acetic acid alkyl (C1-C4) ester with parachlorobenzotrifluoride (PCBTF) as well as combinations of a non-tert-butyl acetate (non-TB Ac) acetic acid alkyl (C1-C4) ester and tert-butyl acetate (TBAc) are preferred. These compositions can be used as diluents in the production of paints, coatings, adhesives, resins, or sealants. Other areas of application include inks, cosmetics, cleaning agents, and explosives. The compositions can be used as substitutes to xylene or toluene.