This patent discloses a novel and effective device and process, which combines the advantages of refrigeration in a synergistic manner with the advantages of hydrogen peroxide and other organic and inorganic peroxygen compounds, resulting in an enhanced ability to reduce and/or eliminate microbial activity and mitigate malodors. This device and process is suitable for the continuous in-situ sanitation and deodorization of enclosed or semi enclosed spaces, which may contain foodstuffs or other putresable items, which would be otherwise adversely affected by the activity of bacteria, mold, mildew or malodors. In particular this invention has application in environments such as refrigerators, cool rooms and freezers, where products are stored for the purpose of extending their shelf life and preventing damage by the activity of microorganisms.