The present invention relates to a soluble granule containing at least one type of active ingredient of sulfonamide herbicide free acid, which comprises: (i) at least one type of active ingredient of sulfonamide herbicide free acid in 2-90 % of anhydrous weight (ii) one or more additives in 0-95 % of anhydrous weight which may be selected from wetting agent, dispersant, lubricant, anticaking agent, chemical stabilizer, and diluents (iii) at least one solid base selected from sodium bicarbonate, sodium carbonate, disodium phosphate, trisodium phosphate, potassium bicarbonate, dipotassium phosphate, potassium phosphate, potassium bicarbonate, potassium hydroxide, hydrated sodium carbonate, sodium acetate, sodium tripolyphosphate, trisodium phosphate dodecahydrate, ammonium hydrogen phosphate, sodium silicate, sodium trisilicate, sodium polyphosphate, sodium hexametaphosphate, and potassium pyrophosphate. The amount of solid base is at least more than 1% of the pesticide composition, in which the weight ratio of the solid base to the sulfonamide herbicide free acid is 1:90-90:1. The sum of anhydrous weight percentages of all the ingredients in the pesticide composition is 100%. The present invention also relates to a preparation method of soluble granule (SG) formulation of the sulfonamide herbicide free acid, which includes the steps of (1) forming the powder ingredient based on the formulation containing at least one type of active ingredient of sulfonamide free acid, at least one type of solid base, and at least one or more additives (2) adding water into the ingredient (3) extruding the wet ingredient through a mold to form the granules and, (4) drying the granules to remove water.本發明涉及一種至少含有一種磺酰胺除草劑游離酸活性組分的可溶性顆粒劑,其包括:(i) 2-90%無水基重量的包含至少一種磺酰胺除草劑游離酸活性組分;(ii) 0-95%無水基重量的一種或多種添加劑,該添加劑選自潤濕劑、分散劑、潤滑劑、防結塊劑、化學穩定劑和稀釋劑;(iii)至少一種固體鹼選自碳酸氫鈉、碳酸鈉、磷酸氫鈉、磷酸鈉、碳酸氫鉀、磷酸氫鉀、磷酸鉀、碳酸氫鉀、氫氧化鉀、水合碳酸鈉、醋酸鈉、三聚磷酸鈉、十二水合磷酸鈉、磷酸氫銨、矽酸鈉、三矽酸鈉、多磷酸鈉、六偏磷酸鈉、焦磷酸鉀;固體鹼的量至少佔農藥組合物的1%以上,且其中固體鹼和磺酰胺除草劑游離酸的重量比為1:90-90: