PURPOSE: A polymer concrete composition is provided to prevent the composition from interfering the growth of plants or microorganisms, and to secure enough strength, durability, and structural stability by containing a polymer, fly ash, and expanded perlite. CONSTITUTION: A polymer concrete composition contains 10-20 parts by weight of water, 5-15 parts by weight of polymer, 15-25 parts by weight of fly ash, 30-40 parts by weight of sand, and 5-20 parts by weight of expanded perlite. The polymer contains 60-70 parts by weight of glycol, 10-20 parts by weight of isocyanate, and 3-7 parts by weight of ionic center. The glycol is obtained by mixing one or two compound selected from polypropylene glycol, polyethylene glycol, ethylene glycol, 1,4-butanediol, or 1,6-multihydroxyhexane. A purification structure includes a vegetation box (100) installed inside a water tank. A gravel layer (110) is formed inside the vegetation box. An inner box (200) is installed inside the gravel layer. The inner box is produced by the polymer concrete composition and includes a through-hole on the side wall.본 발명은 물 10~20중량부, 폴리머 5~15중량부, 플라이 애쉬 15~25중량부, 모래 30~40중량부, 팽창 펄라이트 5~20중량부를 포함하는 것을 특징으로 하는 폴리머 콘크리트 조성물 및 이를 이용한 정화 구조물을 제시함으로써, 식물이나 미생물의 생장을 방해하지 않으면서도, 충분한 강도, 내구성 및 구조적 안정성을 얻을 수 있도록 한다.