The present invention relates to a hollow sphere with a mesoporous structure, and a method for manufacturing the same. The hollow sphere with a mesoporous structure comprises: a shell with plural channels penetrating the shell, wherein the shell comprises: a mesoporous silicon oxide material, and the mesoporous silicon oxide material has a cubic Ia3d symmetry pore structure. In addition, according to the method of the present invention, the aforementioned hollow sphere with the mesoporous structure can be easily obtained by use of a mixture of a cationic surfactant and a non-ionic surfactant.
