3. Compounds of n-tert-butyl-nitroammonium and stereoisomers, their salts, tautometric and positive oxides, and compounds containing these substances. In addition, n-tert-antranilamid compounds or compounds containing these compounds are used to control invertebrate pests. In addition, method 1 of using these compounds: compounds of general formula (1), wherein A1, A2, A3 and A4 are n or CH, but not more than A1, A2, A3 and A4 are n； B1 is n or CH； each R1 is independent of halogen, cyanogen, azido, nitrogen； - SNA； sF5；C1-6alkyl which can be partially or fully halogenated and / or can be substituted with one or more R7 radicals； C3-8 cycloalkyl which can be partially or totally halogenated and / or can be substituted with one or more R7 radicals； C2-6 alkenyl which can be partially or fully halogenated and / or can be substituted with one or more R7 radicals； C2-6 alkynyl which may be partially or fully halogenated and / or can be substituted with one or more R7 radicals； -Si (R14) 2R13； -OR8； -OS (O) nR8； -SR8； -S (O) mR8； -S (O) nN (R9a) R9b； -N (R9a) R9b； -N (R9a) C (= O) R7； -C (= O) R7； -C (= O) OR8； -C (= NR9a) R7； -C (= O) N (R9a) R9b； -C (= S) N (R9a) R9b； phenyl that can be substituted with 1, 2, 3, 4 or 5 radicals R10；It is composed of 3, 4, 5, 6 or 7 members, 1, 2 or 3 heteroatoms or heteroatoms selected from n, s, no, so and SO2. As a ring member, the heterocyclic ring can be replaced by one or more R10 radicals, or two R1 radicals combined in the atom. The adjacent carbon may be a selected set of - ch2ch2ch2ch2ch2 -,-CH=CH-CH=CH---N=CH-CH=CH---CH=N-CH=CH---N=CH-N=CH---OCH2CH2CH2---OCH=CHCH2---CH2OCH2CH2---Oc2CH2O...- 88...-CH2CH2CH2---Ch=CH2---CH2CH2O...-CH=CHO---CH2OCH2...-Ch2c (= O) or--C (3DO) OCH2--O (CH2) or--Sch2CH2CH2---Sch=CHCH2---CH2SC2CH2---Sch2ch2s...-Sch2Sch2...-CH2CH2S...-CH=CHS---CH2SC2...-CH2C (= S) S-,-C (3DS) SCH2--S (CH2) S--CH2CH2N18--CH2CH=N-,-CH=CH-NR18---OCH = N- and -SCH = N-,Thus, together with the carbon atom, a ring of 5 to 6
