A method for forming a large particle complex comprising the steps of combining a hydrolyzed corn starch polymer, a starch/cellulose polymer, a hydrogenated phospholipid, and gum arabic in a cosmetically acceptable carrier to form a premix composition; heating said premix to about 85℃ for about 15 minutes; and cooling the composition to room temperature. The particle complex is useful as a component of a sprayable composition which provides volumizing, hair fixing, and conditioning as a leave-on treatment for human hair.本發明係關於形成大顆粒複合物之方法,其包含以下步驟:將經水解玉米澱粉聚合物、澱粉/纖維素聚合物、氫化磷脂及阿拉伯樹膠(gum arabic)組合於化妝品可接受之載劑中,以形成預混合組合物;將該預混合物加熱至約85℃並保持約15分鐘;及將該組合物冷卻至室溫。該顆粒複合物可用作可噴霧組合物之組份,其為人類頭髮提供免洗型(leave-on)豐盈、髮型固定及調理處理。