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O/W乳化組成物
专利权人:
SHISEIDO COMPANY; LTD.
发明人:
TAKAKURA, TOMIKO,高仓登美子,高倉登美子,KUROSAWA, TAKAFUMI,黑泽卓文,黑澤卓文,YAJIMA, ISAO,矢岛勳,矢島勳,FUJIYAMA, NOZOMI,藤山希
申请号:
TW098136848
公开号:
TWI376238B
申请日:
2009.10.30
申请国别(地区):
TW
年份:
2012
代理人:
摘要:
The present invention provides an oil-in-water emulsion composition being excellent in UV shielding ability, preparation stability and feeling in use, coordinated with an oil organic UV absorbent such as Octocrylene, etc., and a solid organic UV absorbent. The composition of this invention is an oil-in-water emulsion composition containing the following ingredients of (a) to (c), and the average particle diameter of the oil phase containing the ingredient of (a) is 700 nm or less: (a) an Octocrylene (a1)-containing organic UV absorbent being oil-like at 20 DEG C; (b) an organic UV absorbent as a solid at 20 DEG C, selected from (b1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (b2) methylene bis-benzotriazolyl tetramethyl butyl phenol; (c) the polyoxyethylene. polyoxyalkylene alkyl ether block polymer of formula (1) or (2): R1O-(PO)m-(EO)n-H (1) [R1 is a hydrocarbon group with C16-18; PO is a oxypropylene group; EO is an oxyethylene group; PO and EO are adducted to form block shape, m and n respectively represents the average adduction moles of PO and EO, 70 >; m >; 4, 70 >; n >; 10, n >; m] R2O-(AO) p-(EO) q-R3 (2) [R2 and R3 are the same or different, respectively represents a C1-4 hydrocarbon group; AO represents a C1-4 oxyalkylene group; EO represents an oxyethylene group; AO and EO are adducted to form block shape; p and q respectively represents the average adduction moles of AO and EO, 1 &le; p &le; 70, 1 &le; q &le; 70, 0.2 <; (q/(p+q)) <; 0.8.]本發明提供一種O/W乳化組成物,係配合奧克立林(Octocrylene)等之油狀有機紫外線吸收劑與固體有機紫外線吸收劑,而使紫外線防禦能力、製劑安定性以及使用感優異者。本發明之組成物係包含下述成分(a)至(c),且含有成分(a)之油相的平均粒徑在700nm以下,其中,;(a)含有(a1)奧克立林,20℃下為油狀之有機紫外線吸收劑;;(b)選自(b1)雙-乙基己氧基酚甲氧基苯基三、以及(b2)亞甲基雙-苯並三唑基四甲基丁基酚,20℃下為固體之有機紫外線吸收劑;;(c)下述通式(1)或(2)所示之聚氧伸乙基‧聚氧伸烷基烷基醚塊狀聚合物,;R1O-(PO)m-(EO)n-H (1);[R1係碳數16至18之烴基;PO係氧伸丙基、EO係氧伸乙基,PO與EO加成為塊狀;m、n分別為PO、EO之平均加成莫耳數,且70>;m>;4,70>;n>;10,n>;m];R2O-(AO)p-(EO)q-R3 (2);[R2、R3可相同或不同,分別為碳數1至4之烴基;AO係碳數3至4之氧伸烷基、EO係氧伸乙基,AO與EO加成為塊狀;p、q分別為AO、EO之平均加成莫耳數,1≦p≦70、1≦q≦
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