This invention the self compensation type four deuterium connection basis (bonding group) (the 4H- unit) regards the synthesis of the polysiloxane polymer which is included. The polymer which is obtained (the super molecule) between the 4H- units is derived from reversible physical interaction between the polysiloxane chains which are based on interaction shows unique new quality. The polysiloxane of this invention shows the bulk material quality which does not have front example, is used as the gelatinizer of the silicone fluid. Although the gel which is obtained is transparent, it lines up, while possessing the high silicone fluid content where it is not, it possesses satisfactory material quality.本発明は、自己補完型四重水素結合基(bonding group)(4H-単位)を含むシロキサンポリマーの合成に関する。得られるポリマーは、4H-単位間の(超分子)相互作用に基づくポリシロキサン鎖間の可逆的な物理的相互作用から由来する独特の新しい特性を示す。本発明のポリシロキサンは前例のないバルク材料特性を示し、シリコーン流体のゲル化剤として使用される。得られるゲルは、透明であり、並ぶもののない高いシリコーン流体含有量を有しながら、良好な材料特性を有する。