An amphiphilic film structure includes an amphiphilic film, a hydrophobic material layer formed as a first material layer and a hydrophilic material layer formed as a second material layer. The hydrophobic material layer is made of at least one hydrophobic monomer material and the hydrophilic material layer is made of at least one hydrophilic monomer material. The hydrophilic material layer is attached to a predetermined surface for absorbing moisture thereof which can be diffused via the hydrophobic material layer.