Processes for the liberation of oxygen and hydrogen from water are provided allowing for mass scale production using abundant sources of catalyst materials. A metal oxide based anode is formed by the simple oxidation of metal in air by heating the metal for a specified time period. The resultant anode is then contacted with water and subjected to a voltage from an external source or driven by electromagnetic energy to produce oxygen at the surface of the anode by oxidation of water. These processes provide efficient and stable oxygen or hydrogen production.
