The present invention relates to a novel herbicidal composition comprising a herbicidaj active ingredient combination of prosulfocarb and at least one other herbicide selected from picolinafen, fluridone, norflurazon, diflufenican, beflubutaroid, flurochloridone, flujlamone, culcotrione, benzofenap, pyrazolynate, isoxaflutole, pyrazoxyfen, benzobicyclon, arnitrole, fluome-turon, clomazone, aclonifen and isoxachlortole. Each combination is suitable for the selective control of undesited vegetation like weeds (grasses and broad-leaved weeds) in crops of useful plants, for example in crops of rice, cereals and maize.