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ふっ素を含有する配位高分子錯体、ガス吸着材、これを用いたガス分離装置およびガス貯蔵装置
专利权人:
新日鐵住金株式会社;国立大学法人京都大学
发明人:
上代 洋,玉井 宏和,能勢 幸一,北川 進,松田 亮太郎,佐藤 弘志,全 亨濬
申请号:
JP20130042089
公开号:
JP6132596(B2)
申请日:
2013.03.04
申请国别(地区):
日本
年份:
2017
代理人:
摘要:
PROBLEM TO BE SOLVED: To provide: a novel porous polymer metal complex and a gas absorbent having excellent properties using the same; and a gas separation device and a gas storage device each configured by housing the gas absorbent having the properties inside.SOLUTION: There is provided the novel porous polymer metal complex represented by a formula (1)[MXY](1), (in the formula,M is a bivalent transition metal ion, X is an aromatic ligand containing at least one or more perfluoroalkyl group having 1 to 10 carbon atoms and 2 carboxyl groups, Y is a bipyridyl type second ligand, q is 0 or 1, n represents such a property that a lot of constituent units consisting of [MXY]is aggregated, and the size of n is not specifically limited), the metal ion having a laminate type network structure of a two-dimensional square grate in which the 4 ligands are coordinated. There are also provided use of the novel porous polymer metal complex as the gas adsorbent, the gas separation device and the gas storage device each usi
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