This invention provides a fragrance diffusion structure device, which comprises: a container that receives and contains therein a fragrant liquid; a main shaft, which has one end disposed in the container and dipped in the fragrant liquid; and a capillary suction layer disposed on an outer surface of the main shaft. With the aforesaid constitution, the capillary suction effect caused by the capillary suction layer on the fragrant liquid can suck the fragrant liquid along the capillary suction layer and move the fragrant liquid on the main shaft for volatilization to the exterior space. Accordingly, the fragrant liquid or essential oil can be effectively volatized to the air without having to use electrical energy, heating or the addition of hazardous chemicals as the technical means for volatilization, thereby not threatening health and life safety.本發明之芳香擴散結構裝置,其包含一容器,其內設有芳香液體;一主桿體;其一端於係設於該容器內並浸潤接觸該芳香液體;及一毛細吸引層,其設於該主桿體之外側表面;藉前述構成,利用該毛細吸引層對該芳香液體之毛細吸引作用,使該芳香液體沿該毛細吸引層構被吸引前進並於該主桿體揮發散至外側空間;藉此,能有效地將芳香液或精油揮發至空氣中,且無需以電能、加熱或添加有害的化學物品作為揮發之技術手段,故無危害健康、生命安全等疑慮。