KLEE, JOACHIM E.,MAIER, MAXIMILIAN,LALEVEE, JACQUES,FIK, CHRISTOPH P.,FOUASSIER, JEAN PIERRE,MORLET-SAVARY, FABRICE,DIETLIN, CELINE
申请号:
CA2976722
公开号:
CA2976722A1
申请日:
2016.03.30
申请国别(地区):
CA
年份:
2016
代理人:
摘要:
The present invention relates to a dental composition comprising a polymerization initiator system comprising an aromatic tertiary phosphine compound, as well as to a use of said aromatic tertiary phospine compound for the preparation of a photocurable dental composition. In particular, the present invention relates to a dental composition comprising (a) one or more compounds having at least one polymerizable double bond; (b) a polymerization initiator system comprising (b1) a sensitizer; and (b2) an aromatic tertiary phosphine compound of the following formula (I): Z-R (I) wherein Z is a group of the following formula (II) R(Ar)P-(II) wherein R1 represents a substituted or unsubstituted hydrocarbyl group; Ar represents a substituted or unsubstituted aryl or heteroaryl group; R is an aryl group, which may be substituted by one or more groups selected from a hydroxyl group, an amino group, a NR2R3 group (wherein R2 and R3, which may be the same or different, are selected from C1-6 alkyl groups), a carboxyl group, and a group having a polymerizable double bond; wherein the group R and Ar may be substituted by one or more groups selected from a hydroxyl group, an oxo group, a NR2R3 group (wherein R2 and R3, which may be the same or different, are selected from a hydrogen atom and C1-6 alkyl groups), a carboxyl group, and a group having a polymerizable double bond, and L may be substituted by one or more groups selected from a hydroxyl group,an oxo group, a NR2R3 group (wherein R2 and R3, which may be the same or different, are selected from a hydrogen atom and C1-6 alkyl groups), a carboxyl group, and a group having a polymerizable double bond.