您的位置: 首页 > 农业专利 > 详情页

MANUFACTURING METHOD OF NITROGEN-CONTAINING TITANIUM OXIDE POWDER
专利权人:
三菱マテリアル電子化成株式会社;MITSUBIHI MATERIALS ELECTRONIC CHEMICALS CO LTD
发明人:
KAGEYAMA KENSUKE,影山 謙介,KONISHI TAKASHI,小西 隆史,ISHIGURO SHIGEKI,石黒 茂樹
申请号:
JP2018047657
公开号:
JP2019156690A
申请日:
2018.03.15
申请国别(地区):
JP
年份:
2019
代理人:
摘要:
PROBLEM TO BE SOLVED: To provide a method for highly productive, mass manufacturing nitrogen-doped titanium oxide powder having high photocatalytic activity when irradiated with a visible light and excellent UV light shield property especially when irradiated with a near range (UV-A) UV light which is close to a visible light among UV lights.SOLUTION: In the method, a titanium oxide powder is subjected to nitriding reduction in an ammonia gas atmosphere with a heating temperature of 800°C or over and 1200°C or under to manufacture a titanium oxynitride powder containing nitrogen of 8 mass% or over. This titanium oxynitride powder is subjected to oxidization in an oxidizing atmosphere with a heating temperature of 500°C or over and 700°C or under to manufacture a nitrogen-containing titanium oxide powder containing nitrogen at a rate of 0.2 mass% or over and 0.8 mass% or under and a lightness index L* value measured in accordance with CIE 1976 L*a*b* color space ( measurement light source C: color temperature 6774K) of 70 or over. When the manufactured nitrogen-containing titanium oxide powder is subjected to measurement as an aqueous dispersion containing the powder dispersed in a water at a concentration of 0.1 mass % in a glass cell having an optical path of 1 mm, its transmittance of a light at a wavelength of 400nm is 40% or under, and its transmittance of a visible light at a wavelength of 550nm is 40% or over and 85% or under.SELECTED DRAWING: Figure 1COPYRIGHT: (C)2019,JPO&INPIT【課題】可視光を照射したときの光触媒活性が高く、かつ紫外線の中でも特に可視光に近い範囲(UV-A)の紫外線を照射したときの紫外線遮蔽性に優れた窒素ドープ酸化チタン粉末を高い生産性で大量に生産できる。【解決手段】チタン酸化物粉末をアンモニアガス雰囲気下、800℃以上1200℃以下の加熱温度で窒化還元して窒素を8質量%以上含有する酸窒化チタン粉末を製造し、この酸窒化チタン粉末を酸化性雰囲気下、500℃以上700℃以下の加熱温度で酸化して、窒素を0.2質量%以上0.8質量%以下の割合で含有し、CIE 1976 L*a*b*色空間(測定用光源C:色温度6774K)における明度指数L*値が70以上である窒素含有型酸化チタン粉末を製造する。製造された窒素含有型酸化チタン粉末を粉末濃度0.1質量%で水に分散した水分散液を光路長1mmのガラスセルに入れて測定をしたときに波長400nmの光透過率が40%以下であり、波長550nmの可視光透過率が40%以上85%以下である。【選択図】図1
来源网站:
中国工程科技知识中心
来源网址:
http://www.ckcest.cn/home/

意 见 箱

匿名:登录

个人用户登录

找回密码

第三方账号登录

忘记密码

个人用户注册

必须为有效邮箱
6~16位数字与字母组合
6~16位数字与字母组合
请输入正确的手机号码

信息补充