The invention relates to a composite and oral care compositions for use in the mouth to retard the accumulation of dental plaque and/or calculus. The composite is a microaggregate comprising polymer coated, surfactant stabilized particles of a substantially insoluble metal, metal salt or metal oxide, for example zinc oxide. Also methods for retarding the accumulation of dental plaque and/or calculus are provided.本發明涉及一種使用於口腔中的複合物及口腔護理組成物,以延緩牙菌斑及/或結石之累積。該複合物係一種微聚集體,其含有本質不溶性金屬、金屬鹽或金屬氧化物,例如:氧化鋅,經聚合物塗層,經介面活性劑安定化的顆粒。亦提供延緩牙菌斑及/或結石累積之方法。