A herbicidal composition and applying method thereof is related to the herbicidal composition including：an antidotically effective amount of one or more safeners from the group of the phosphorated esters of the formula (I), wherein T and T1 are independently selected from the group of hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl, and alkynyl, U is O or S, and V, W, X, Y, and Z are independently selected from the group of hydrogen, halogen, alkyl, haloalkyl, and alkoxy； and one or more sulfonamide or sulfonylurea herbicides selected from the group consisting of amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron-methyl, ethoxysulfuron, flupyrsulfuron-methyl, flazasulfuron, foramsulfuron, halosulfuron-methyl, imazosulfuron, iodosulfuron-methyl, mesosulfuron-methyl, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron-methyl, prosulfuron, thifensulfuron-methyl, tribenuron-methyl, trifloxysulfuron, triflusulfuron-methyl, triosulfuron, rimsulfuron, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, and combinations thereof, and methods for using the same.一種除草組合物及其使用方法，其中除草組合物包含：解毒有效量的一種或多種安全劑(safener)，且安全劑(safener)係選自下列式(I)的磷酸酯類，其中T和T1獨立地選自氫、烷基、鹵代烷基、烷氧基烷基、烯基和炔基、U是O或S，且V、W、X、Y和Z獨立地選自氫、鹵素、烷基、鹵代烷基和烷氧基；以及一種或多種磺胺或磺醯脲除草劑，其選自醯嘧磺隆、四唑嘧磺隆、苄嘧磺隆、氯嘧磺隆、氯磺隆、醚磺隆、環丙嘧磺隆、胺苯磺隆、乙氧嘧磺隆、氟啶嘧磺隆、啶嘧磺隆、醯胺磺隆、氯吡嘧磺隆、唑吡嘧磺隆、甲基碘磺隆、甲磺胺磺隆、甲磺隆、煙嘧磺隆、環氧嘧磺隆、氟嘧磺隆、氟丙磺隆、噻吩磺隆、苯磺隆、三氟啶磺隆、氟胺磺隆、醚苯磺隆、碸嘧磺隆、氯酯磺草胺、雙氯磺草胺、雙氟磺草胺、氟唑啶草、磺草唑胺、五氟磺草胺及其組合。
