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炭化水素界面活性剤を用いたフルオロモノマーの水性重合
专利权人:
イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.DU PONT DE NEMOURS AND COMPANY
发明人:
ポール ダグラス ブラザーズ,スバシュ ヴィシュヌ ガンガル,ディプティ ディリップ カスニス
申请号:
JP20130538851
公开号:
JP6109073(B2)
申请日:
2011.11.09
申请国别(地区):
日本
年份:
2017
代理人:
摘要:
A process is provided for the polymerization of fluoromonomer to an dispersion of fluoropolymer particles in an aqueous medium in a polymerization reactor, by (a) providing the aqueous medium in the reactor, (b) adding the fluoromonomer to the reactor, (c) adding initiator to the aqueous medium, the combination of steps (b) and (c) being carried out essentially free of hydrocarbon-containing surfactant and resulting in the kickoff of the polymerization of the fluoromonomer, and (d) metering hydrocarbon-containing surfactant into the aqueous medium after the kickoff of polymerization, e.g. after the concentration of the fluoropolymer in the aqueous medium is at least 0.6 wt %, the metering being at a rate reducing the telogenic activity of said surfactant while maintaining surface activity.
来源网站:
中国工程科技知识中心
来源网址:
http://www.ckcest.cn/home/

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