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Dispersion of adsorbing emulsion polymer particles
专利权人:
Rohm and Haas Company
发明人:
Brownell Arnold S.,Tiwary Yogesh
申请号:
US201514732838
公开号:
US9932431(B2)
申请日:
2015.06.08
申请国别(地区):
美国
年份:
2018
代理人:
Willis Reid S.
摘要:
The present invention is a composition comprising a stable aqueous dispersion of polymer particles having a core comprising structural units of: a) a phosphorus acid monomer, b) an acid monomer, c) a multiethylenically unsaturated monomer; and d) a polymerizable ethylenically unsaturated bulk monomer; and a shell comprising structural units of a1) a sulfur acid monomer, and b1) a polymerizable ethylenically unsaturated bulk monomer; wherein the core protuberates from the shell and the ratio of the structural units of the sulfur acid monomer to structural units of carboxylic acid monomer in shell is at least 0.2:1. Control of the proportion of sulfur acid monomer units to carboxylic acid monomer units results in an improvement in the viscosity stability of paint formulations containing latexes possessing acorn morphology without sacrificing hiding.
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