Disclosed is a fungicidal composition containing a fungicidally effective amount of a 6-methyl-4,9-dioxo-1,5-dioxonane derivative compound of Formula I, IV or V and at least one triazole fungicide selected from the group consisting of epoxiconazole, prothioconazole and prochloraz, provides synergistic control of selected fungi. The fungi which is controlled may include: wheat brown rust (Puccinia recondita); stripe rust of wheat (Puccinia striiformis); leaf blotch of wheat (Mycosphaerella graminicola; Septoria tritici); glume blotch of wheat (Leptosphaeria nodorum; Stagonospora nodorum); spot blotch of barley (Cochliobolus sativum; Helminthosporium sativum); leaf spot of sugar beets (Cercospora beticola); leaf spot of peanut (Mycosphaerella arachidis; Cercospora arachidicola); cucumber anthracnose (Glomerella lagenarium; Colletotrichum lagenarium) and black sigatoka disease of banana (Mycosphaerellafijiensis).