The present disclosure relates to pyrrolo-nitrogenous heterocyclic derivatives pharmaceutical salts, preparation processes and pharmaceutical use thereof. Specifically, the present disclosure relates to (R,Z)-2-(5-fluoro-2-oxo-1,2-dihydro-indol-3-ylidenemethyl)-5-(2-hydroxy-3-morphol in-4-yl-propyl)-3-methyl-5,6,7,8-tetrahydro-1H-pyrrolo[3,2-c]azepin-4-one derivatives pharmaceutical salts presented by formula (I), the uses for treatment especially for protein kinase inhibitors.本發明涉及吡咯並N雜環類衍生物的可藥用的鹽、其製備方法及其在醫藥上的應用。具體而言,本發明涉及式(I)所示的(R,Z)-2-(5-氟-2-側氧基-1,2-二氫-吲哚-3-次甲基)-5-(2-羥基-3-嗎啉-4-基-丙基)-3-甲基-5,6,7,8-四氫-1H-吡咯並[3,2-c]吖庚因-4-酮的可藥用的鹽,其製備方法以及作為治療劑特別是作為蛋白激酶抑制劑的用途。