An anti-bacterial photocatalytic coating apparatus includes a chassis and a container containing an anti-bacterial photocatalytic coating liquid. There is a means mounted on the chassis for applying plasma-based surface activation unto a stationary surface underneath the chassis. There is also a means mounted on the chassis for spraying the anti-bacterial photocatalytic coating liquid on the surface underneath the chassis. A third means mounted on the chassis for shining UV light onto the surface sprayed with the anti-bacterial photocatalytic coating liquid. Optionally, there is a means mounted on the chassis for baking the surface sprayed with the anti-bacterial photocatalytic coating liquid. The plasma-based surface activation may be replaced with the spraying of a non-photocatalytic prime coating. The equivalent anti-bacterial photocatalytic coating processes for coating stationary surface are also introduced.