The present invention provides a solar environment-friendly sterilizing deodorizing shoe rack which comprises a base, a supporting rod and an air storage tank arranged at the top of the supporting rod. A plurality of support air-conveying pipes are evenly distributed on the periphery of the air storage tank, and the top end of each support air-conveying pipe is provided with a shoe bracket; the top of the air storage tank is provided with an air storage tank seal cover, and a solar panel is disposed outside the air storage tank seal cover; a battery, a circuit board, an ozone generator and a fan are arranged in the air storage tank; the battery is electrically connected with the circuit board, the ozone generator and the fan; and the solar panel is electrically connected with the battery. According to the intelligent environment-friendly sterilizing deodorizing shoe rack of the present invention, the solar panel is utilized to charge the battery, and thus energy is provided for the intelligent environment-friendly sterilizing deodorizing shoe rack; the ozone generator is utilized to generate ozone, the fan is utilized to blow the ozone to the support air-conveying pipes, and thus the shoes on the top shoe brackets are filled with ozone and sterilized and deodorized.