The present invention provides optical material, and it includes optical functional crosslinking supramolecular structure and components, is used for united optical imagery and treatment. Supramolecular structure and component of the invention includes optical functional shell-crosslinking micella, and wherein optical function is realized by integrating one or more linkers, and the linker includes one or more optical activities part. The invention also includes imaging and treatment methods, use one or more optical materials of the invention, which includes optical functional shell-crosslinking micella with the therapeutic agent combined.