Compositions comprising a polyvinyl alcohol in combination with a biocide which is a plasticizer, such as a quaternary ammonium compound, or in combination with a biocide and a compatible plasticiser, and wherein the biocide forms a complex with the polyvinyl alcohol, said combination having been heated to above its melting point, said composition having a surface which remains biostatic or biocidal for at least 7 days. A hot melt of the composition may be cast or applied as a film or coating or may be extruded moulded or otherwise into articles. Volatiles formed during heating may be removed from the combination e.g. by low pressure.一種包含有與係為一塑化劑之殺生物劑(諸如四級銨化合物)組合或是與一殺生物劑和一可相容塑化劑組合之聚乙烯醇的組成物,且其中該殺生物劑會與聚乙烯醇形成一複合物,該組合係被加熱至其之熔點以上,該組成物係具有一可維持細菌抑制性或殺菌性至少7天的表面。熱融狀的該組成物可以被鑄造或施用成為一薄膜或塗覆物,或以模製或其他方式擠出成為一物件。在加熱期間形成的揮發物藉由例如低溫由該組合中移除。