The present invention relates to an odorant composition comprising (i) at least one α,β-unsaturated compound selected from α,β-unsaturated ketones or from α,β-unsaturated aldehydes or from mixtures thereof, and (ii) at least one thiol group-containing odorant, an agent containing said odorant composition, and to the use of a detergent or cleaning agent, an air care product, a cosmetic agent or an adhesive containing such an odorant composition.