PROBLEM TO BE SOLVED: To provide an adhesive organic/inorganic composite gel in which there is no damage which is a pain or keratin peeling to the skin in the case of peeling, the rash of skin is not produced, and the adhesion to the skin is good and to provide a method of manufacturing the same.SOLUTION: The adhesive organic inorganic compound gel includes: a water-soluble low volatile compound (C) which shows the volatility of at most 0.1 g/h at 60°C in the atmosphere and per 1 cm2 in the open system of one barometric pressure (at most 0.1 g/cm2×hr×60°C×1 atm) and/or water inside the three-dimensional network structure formed by compounding a polymer of a water-soluble radically polymerizable monomer (A) and a water-swellable clay mineral (B), and is characterized by including a water-soluble organic polymer (D) having an amide bond on the whole surface or part of the gel.COPYRIGHT: (C)2012,JPO&INPIT【課題】剥離の際の皮膚に対する痛みや角質剥離といったダメージが無く、皮膚のかぶれを生じさせず、且つ皮膚に対する接着力が良好である粘着性有機無機複合体ゲル、及びその製造方法を提供する。【解決手段】水溶性ラジカル重合性モノマーの重合体(A)と、水膨潤性粘土鉱物(B)とが複合化して形成した三次元網目構造中に、大気中で60℃、且つ1気圧の開放系における1cm2当たり、毎時0.1g以下(0.1g/cm2・hr・60℃・1atm以下)の揮発性を示す水溶性の低揮発性化合物(C)及び/又は水を含有する粘着性有機無機複合ゲルであって、該ゲルの表面全体又は一部にアミド結合を有する水溶性有機高分子(D)を包含することを特徴とする粘着性有機無機複合ゲル。【選択図】なし