The present invention is directed to a method of reduction of frizz and improving hair conditioning wherein a hair treatment composition comprising a silicone emulsion with droplets having an average diameter of less than about 50 nanometers in an carrier wherein the silicone emulsion comprises a crosslinked organopolysiloxane made from various reactive compounds, wherein each compound is comprised of one or more units represented by the following general formula:R1nR2mR3p(OR4)qSiO[4-(m+n+p+q)]/2 whereR1 is morpholinomethyl having the structure:R2 is —(CH2)3—NH—(CH2)2NH2 —(CH2)3—NH2 R3 is methyl R4 is hydrogen, methyl, ethyl or propyl n is 0, 1, or 2 m is 0, 1, or 2 p is 0, 1, or 2 q is 0, 1, 2 or 3 n+m+p+q is less than or equal to 3 and wherein the crosslinked organopolysiloxane comprises on average at least one radical R1 per molecule and wherein the method comprises the following steps: a) applying the hair treatment composition to hair by spraying or spreadingb) allowing hair to dry by air or heat.
