The present invention provides a topical anti-eczemic composition comprising a substance derived from a plant material of Cinnamomum camphor a in an amount ranging between 1 and 30 % with respect to the total weight of the composition a substance derived from a plant material of Uncaria gambler in an amount ranging between 1 and 30 % with respect to the total weight of the composition and at least two oxides of lead (Pb) selected from the group consisting of lead (II) oxide (PbO), lead (II, IV) oxide (Pb203) and lead (IV) dioxide (Pb02) in an amount of 5 to 50 % with respect to the total weight of the composition. The present invention also provides a process for preparing a topical anti-eczemic composition.