Provided are an extraction structure, an extraction module, and a liquid pretreatment device relating to the liquid component testing technical field. The extraction structure comprises a cavity and a first pore passage. The extraction module comprises an extraction module body, successively bottom up, including a first cavity provided therein with a second filter layer, a first pore passage provided therein with a first filter layer, and a second cavity provided therein with an extractant layer and a porous filter disc; the first and second filter layers contain therein an expansive agent; and the diameter of the first filter layer is smaller than that of the second filter disc. The liquid pretreatment device comprises a storage tank, a transfer device and the extraction module. Between the transfer device and the extraction module is provided a filter membrane for filtering and supporting.