MOSZNER, NORBERT, PROF. DR.,KLAPDOHR, SIMONE, DR.,SALZ, ULRICH, DR.,ZIMMERMANN, JÖRG,RHEINBERGER, VOLKER M., DR.,MÜHLHAUPT, ROLF,PROF. DR.
申请号：
EP04020183.2
公开号：
EP1510197B1
申请日:
2004.08.25
申请国别(地区):
EP
年份:
2016
代理人:
摘要：
A polymerizable composition containing by weight (a) an (optionally radically polymerizable) silane or aluminum, zirconium or titanium compound (1-80%), (b) a radical polymerization initiator (0.1-5%) and (c) further radically polymerizable monomer(s) (0-60%) also contains (d) a radically polymerizable monomer (1-50%) with a phosphonic or sulfonic acid group and is such that the polycondensate of (a) and/or the monomer (c) is fluorine substituted. A polymerizable composition containing by weight a radically polymerizable silane of formula (I), a silane of formula (II) and/or aluminum, zirconium or titanium compound of formula (III) or (IV) (1- 80%)； a radical polymerization initiator (0.1-5%)； and further radically polymerizable monomer(s) (0-60%) also contains (d) a radically polymerizable monomer (1-50%) with a phosphonic or sulfonic acid group and of formula (V) and is such that the polycondensate obtained from (a) and/or the monomer (c) is fluorine-substituted. ((R 1>；) a-R 2>；) m(R 3>；) nSiX (4-m-n)(I) (R 4>；) (4-p)SiY p(II) AlZ 3(III) Me(O) rZ s(IV) (R 5>；) t-Sp-A w(V) R 1>；a radically polymerizable group； R 2>；is absent or : a di- or tri-valent optionally substituted 1-30C hydrocarbon residue optionally chain-interrupted by one or more heteroatoms or by a carboxylic acid ester (-CO-O- or -O-CO-), carboxylic acid amide (-CO-NR 7>；- or -NR 7>；-CO-), urethane (-NH-CO-O- or -O-CO-NH-) and/or amino (-NR 8>；-) groups； R 7>；and R 8>；H or 1-5C alkyl； R 3>；1-12C alkyl, 3-12C cycloalkyl or 6-12C aryl, alkaryl or aralkyl； X : halogen or 1-3C alkoxy； a : 1 or 2； m : 1, 2 or 3； n : 0, 1 or 2, with m + n=3； R 4>；1-12C alkyl or phenyl optionally substituted by F； Y : halogen or 1-3C alkoxy； p : integer 1-4； Z : halogen or 1-6C alkoxy； Me : Zr or Ti； r : 0 or 1； s : integer 1-4 with the sum of the valencies of residues O and Z corresponding to the valency of Me； R 5>；a radically polymerizable group； t : integer 1-5； Sp : 1-30C hydrocarbon group
