MOSZNER, NORBERT, PROF. DR.,KLAPDOHR, SIMONE, DR.,SALZ, ULRICH, DR.,ZIMMERMANN, JÖRG,RHEINBERGER, VOLKER M., DR.,MÜHLHAUPT, ROLF,PROF. DR.
申请号:
EP04020183.2
公开号:
EP1510197B1
申请日:
2004.08.25
申请国别(地区):
EP
年份:
2016
代理人:
摘要:
A polymerizable composition containing by weight (a) an (optionally radically polymerizable) silane or aluminum, zirconium or titanium compound (1-80%), (b) a radical polymerization initiator (0.1-5%) and (c) further radically polymerizable monomer(s) (0-60%) also contains (d) a radically polymerizable monomer (1-50%) with a phosphonic or sulfonic acid group and is such that the polycondensate of (a) and/or the monomer (c) is fluorine substituted. A polymerizable composition containing by weight a radically polymerizable silane of formula (I), a silane of formula (II) and/or aluminum, zirconium or titanium compound of formula (III) or (IV) (1- 80%); a radical polymerization initiator (0.1-5%); and further radically polymerizable monomer(s) (0-60%) also contains (d) a radically polymerizable monomer (1-50%) with a phosphonic or sulfonic acid group and of formula (V) and is such that the polycondensate obtained from (a) and/or the monomer (c) is fluorine-substituted. ((R 1>;) a-R 2>;) m(R 3>;) nSiX (4-m-n)(I) (R 4>;) (4-p)SiY p(II) AlZ 3(III) Me(O) rZ s(IV) (R 5>;) t-Sp-A w(V) R 1>;a radically polymerizable group; R 2>;is absent or : a di- or tri-valent optionally substituted 1-30C hydrocarbon residue optionally chain-interrupted by one or more heteroatoms or by a carboxylic acid ester (-CO-O- or -O-CO-), carboxylic acid amide (-CO-NR 7>;- or -NR 7>;-CO-), urethane (-NH-CO-O- or -O-CO-NH-) and/or amino (-NR 8>;-) groups; R 7>;and R 8>;H or 1-5C alkyl; R 3>;1-12C alkyl, 3-12C cycloalkyl or 6-12C aryl, alkaryl or aralkyl; X : halogen or 1-3C alkoxy; a : 1 or 2; m : 1, 2 or 3; n : 0, 1 or 2, with m + n=3; R 4>;1-12C alkyl or phenyl optionally substituted by F; Y : halogen or 1-3C alkoxy; p : integer 1-4; Z : halogen or 1-6C alkoxy; Me : Zr or Ti; r : 0 or 1; s : integer 1-4 with the sum of the valencies of residues O and Z corresponding to the valency of Me; R 5>;a radically polymerizable group; t : integer 1-5; Sp : 1-30C hydrocarbon group